二苯并-18-皇冠-6CAS14187-32-7

CAS:14187-32-7
Molecular Formula:C20H24O6
Molecular Weight:360.4
EINECS:238-041-3

Synonyms:Dibenzo-18-crown-6, 98%, reagent grade; ibenzo-18-crown-6; Dibenzo[a,j]-1,4,7,10,13,16-hexaoxacyclooctadeca-2,11-dien; Dibenzo-18-crown-8; Dibenzo-18-crown-ether-6; 2,5,8,15,18,21-; hexaoxatricyclo[20.4.0.0,1]hexacosa-1(26),9,11,13,22,24-hexaene; Dibenzanthracene-18-Crown-6

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1.what is of  Dibenzo-18-crown-6 with CAS 14187-32-7?

Dibenzo-18-crown-6 is the raw material for the synthesis of diaminodibenzo-18-crown-6. Diaminodibenzo-18-crown-6 is an important crown ether compound and an important intermediate raw material for the synthesis of crown ether derivatives. Its synthesis method is to use dibenzo-18-crown-6 as a raw material, and to obtain it through nitration and reduction reaction. The reduction method used is Pd/C reduction method, which is limited by the expensive catalyst price. The traditional synthesis method of dibenzo-18-crown-6, the raw material of diaminodibenzo-18-crown-6, is a reflux reaction under nitrogen protection, which has harsh conditions, complicated steps, long reaction cycle, high temperature and low yield. Ultrasonic synthesis is a new type of synthesis method developed in recent years. It has the advantages of good directionality, large energy and strong penetration ability. It is more convenient and easy to operate than traditional organic synthesis methods. The experimental equipment is also relatively simple and easy to control. It is more and more widely used in organic synthesis.

2.说明二苯并-18-皇冠-6CAS14187-32-7

熔点 162至164°C(亮。)
沸点 380-384°C(679毫米汞柱)
密度 1.1801(粗略的估计)
折射率 线1.5200(估计)
Fp 380-384°C/679mm
储存温度。 商店下面+30°C。
溶解度 0.007g/l
形式 毛茸茸的粉末
颜色 白稍微米色
水溶解度 微溶
λmax 277nm(CH2Cl2)(亮。)
敏感 空敏感
Merck 14,2602
BRN 1162153
InChIKey YSSSPARMOAYJTE-UHFFFAOYSA-N
CAS参考数据库 14187-32-7(CAS数据库的参考)

3.应用程序

‌1. Metal ion complexing agent‌: Dibenzo-18-crown-6 can form stable complexes with alkali metal ions (such as potassium and sodium) and is often used in the extraction and separation of metal ions. For example, it can complex with potassium ions to promote the extraction and separation of salts.

‌2. Phase transfer catalyst‌: Dibenzo-18-crown-6 acts as a phase transfer catalyst in organic catalytic reactions to promote the efficiency and yield of two-phase reactions. For example, it is used in the synthesis of monoazaporphyrins and ion transmembrane migration‌23.

‌3. Ion sensor‌: Compounds based on Dibenzo-18-crown-6 can be used to prepare ion sensors to detect and measure the presence and concentration of specific metal ions.

‌4. Chemical analysis‌: Dibenzo-18-crown-6 is used in extraction and separation processes in analytical chemistry to extract and enrich target compounds or metal ions for subsequent analysis and detection‌

4.包装

Usually packed in 25kg/drum,and also can be do customized package

Dibenzo-18-crown-6 with CAS 14187-32-7-package

二苯并-18-皇冠-6CAS14187-32-7
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