4-Bromostyrene is a para-halogenated styrene derivative. The proton spectra of 4-bromostyrene exhibits dipolar couplings consistent with planar ground state structures, only if the torsional motion of lowest frequency occurs at about 80cm-1. It undergoes Heck reaction with 2-bromo-6-methoxynaphthalene in the presence of sodium acetate and Hermann′s catalyst in N,N-dimethylacetamide to afford diarylethene.
Indeling:Chemische Auxiliary Agent
CAS No.:350-51-6
Other Names:BROMOSTYRENE-4
MF:C8H7Br
EINECS-Nr.:218-022-6
Zuiverheid:96%
Plaats van Oorsprong:Shandong, China
Type:Carbon Zwart
Gebruik:De Oppervlakteactieve Stoffen
Model Number:HHYYT020103
Product Name::4-Bromostyrene
CAS::2039-82-9
MF::C8H7Br
MW::183.05
EINECS::218-022-6
| Smeltpunt | 4.5 °C |
| Boiling point | 89 °C16 mm Hg(lit.) |
| density | 1.40 g/mL at 20 °C |
| refractive index | n20/D 1.594(lit.) |
| Fp | 168 °F |
| storage temp. | -20°C |
| solubility | Miscible with ethanol, ether and benzene. |
| form | Liquid |
| color | light greenish-yellow |
| BRN | 1634204 |
| InChIKey | WGGLDBIZIQMEGH-UHFFFAOYSA-N |
| CAS DataBase Verwijzing | 2039-82-9(CAS DataBase Reference) |
| NIST Chemistry Reference | 4-BrC6H4CH=CH2(2039-82-9) |
200 kg/trommel, 16tons/20'container
4-Bromostyrene is widely utilized in the synthesis of nitroolefins by alkene cross-metathesis. It plays an important role in the Heck reaction to the synthesis of poly(1,4-phenylenevinylene). It is employed in the structure activity relationships (SAR) study of the chemical and biochemical properties of the vinyl group of styrene.
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